PBT巴斯夫B4030G6(德国巴斯夫塑料)
聚对苯二甲酸丁二醇酯(PBT)是通用的工程塑料。
1 PBT的工艺特性
PBT具有明显的熔点,熔点为225~235℃,是结晶型材料,结晶度可达40%。
PBT熔体的粘度受温度的影响不如剪切应力那么大,因此,在注塑中,注射压力对PBT熔体流动性影响是明显。
PBT在熔融状态下流动性好,粘度低,仅次于尼龙,在成型易发生“流延”现象。
PBT成型制品各向异性。PBT在高温下遇水易降解。
2注塑机
选用螺杆式注塑机时。应考虑如下几点。
①制品的用料量应控制在注塑机额定注射量的30%~80%。不宜用大注塑机生产小制品。
②应选用渐变型三段螺杆,长径比为15~20,压缩比为2.5~3.0。
③应选用自锁式喷嘴,并带有加热控温装置。
④在成型阻燃级PBT时,注塑机的有关部件应经防腐处理。
3制品与模具设计
①制品的厚度不宜太厚,PBT对缺口很敏感,因此,制品的直角等过渡处应采用圆弧连接。
②PBT的成型收缩率较大,在1.7%~2.3%,模具要有一定的脱模斜度。
③模具需要设排气孔或排气槽。
④浇口的口径要大。
⑤模具需设置控温装置。模具温度不能超过100℃。
⑥阻燃级PBT成型,模具表面要镀铬,以防腐。
4原料准备
注塑前要进行干燥、要将水分含量控制在0.02%以下。采用热风循环干燥时,当温度为105℃、120℃或140℃时,所对应的时间不超过8h、5h、3h。料层厚度低于30mm。
5注塑工艺参数
①注射温度PBT的分解温度为280℃,所以实际生产中一般控制在245~260℃之间。
②注射压力注射压力一般为50~100MPa。
③注射速率PBT冷却速度快,因此要采用较快的注射速率。
PBT INJECTION PROCESS IN GERMANY: Before injection, PBT must be dried for 3 hours at 110 ~ 120 °c, the processing temperature is 250 ~ 270 °C, and the mold temperature is 50 ~ 75 °C. If the temperature of the nozzle is not controlled properly (on the low side) , the runner (nozzle) is easy to cool and solidify, and the nozzle will be stopped up. If the temperature of the feeding barrel exceeds 275 °C or the residence time of the molten material in the feeding barrel exceeds 30 minutes, the material will easily decompose and become brittle. When PBT is injected into plastic, it is necessary to use a large water inlet, not a hot runner system. The die should have a good exhaust, and should be formed under the conditions of "high-speed, medium-pressure and medium-temperature" . The fireproof material or the PBT water inlet with glass fiber should not be recycled, when the machine stops, it is necessary to use pe or PP material to clean the material pipe in time to avoid carbonization. POLYBUTYLENE terephthalate (PBT) , also known as polytetramethylene terephthalate (polytetramethylene terephthalate) , is made from terephthalic acid and 1,4-butanediol. Important thermoplastic polyester, one of the top five engineering plastics.
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